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Diethylzinc - Disposable Anal Speculum Manufacturer - China Disposable Dental Impression Tray
Synthesis
Edward Frankland first reported the compound in 1848 from zinc and ethyl iodide, the first organozinc compound discovered. He improved the synthesis by using diethyl mercury as starting material The contemporary synthesis consists of the reaction of a 1:1 mixture of ethyl iodide and ethyl bromide with a "zinc-copper couple," a source of reactive zinc.
Reactions
Diethylzinc is used in organic synthesis as a source of the ethyl synthon in addition reactions to carbonyl groups. It is less nucleophilic than ethyllithium and related Grignard reagents. For example in the asymmetric addition to benzaldehyde and imines.
With diiodomethane it forms a Simmons-Smith reagent.
Other uses
Because of its high reactivity toward air, it was used in small quantities as a hypergolic or "self igniting" liquid rocket fuel -- it ignites on contact with oxidiser, so the rocket motor need only contain a pump, without a spark source for ignition.
Diethylzinc was also investigated for a time by the United States Library of Congress as a potential means of mass deacidification of books printed on wood pulp paper. Initial experiments involved placing books within a vacuum chamber and exposing them to diethylzinc vapour. In theory, the vapour would react with acid residues in the paper, neutralizing them and leaving only slightly alkaline zinc oxide residues in the paper. Results were initially promising, showing the pH of the paper to be increased to 7.5. Larger-scale experiments did not go as well; prototypes built for the Library of Congress by Northrup left "tide marks" on the pages, caused the bindings and boards to split and warp, and left unpleasant odours. There was also some evidence of the pages being physically weakened, even as their acidity was reduced. In addition, it became clear that any large-scale deacidification process involving diethylzinc would require the transport by truck of enormous volumes of the chemical, which could not be done safely due to its volatility.
Most infamously, the final prototype suffered damage in a series of explosions from contact between trace amounts of diethylzinc and water vapor in the chamber. The project was abandoned.
In microelectronics, diethylzinc is used as a doping agent.[citation needed]
Safety
Diethylzinc reacts violently with water and easily ignites upon contact with air. It should therefore be handled using inert atmosphere techniques.
References
^ E. Frankland (1850). "On the isolation of the organic radicals". Quarterly Journal of the Chemical Society 2: 263. doi:10.1039/QJ8500200263.
^ E. Frankland, B. F. Duppa (1864). "On a new reaction for the production of the zinc-compounds of the alkyl-radical". Journal of the Chemical Society 17: 2936. doi:10.1039/JS8641700029.
^ C. R. Noller (1943), "Diethyl Zinc", Org. Synth., http://www.orgsyn.org/orgsyn/orgsyn/prepContent.asp?prep=cv2p0184 ; Coll. Vol. 2: 184
^ Masato Kitamura, Hiromasa Oka, Seiji Suga, and Ryoji Noyori (2004), "Catalytic Enantioselective Addition of Dialkylzincs to Aldehydes Using (2S)-()-3-exo-(Dimethylamino)isoborneol [(2S)-DAIB]: (S)-1-Phenyl-1-propanol", Org. Synth., http://www.orgsyn.org/orgsyn/orgsyn/prepContent.asp?prep=v79p0139 ; Coll. Vol. 10: 635
^ Jean-Nicolas Desrosiers, Alexandre Ct, Alessandro A. Boezio, and Andr B. Charette (2005), "Preparation of Enantiomerically Enriched (1S)-1-Phenylpropan-1-amine Hydrochloride by a Catalytic Addition of Diorganozinc Reagents to Imines", Org. Synth. 83: 5, http://www.orgsyn.org/orgsyn/orgsyn/prepContent.asp?prep=v83p0005
^ Andr B. Charette and Hlne Lebel (2004), "(2S,3S)-(+)-(3-Phenylcyclopropyl)methanol", Org. Synth., http://www.orgsyn.org/orgsyn/orgsyn/prepContent.asp?prep=v76p0086 ; Coll. Vol. 10: 613
^ Yoshihiko Ito, Shotaro Fujii, Masashi Nakatuska, Fumio Kawamoto, and Takeo Saegusa (1988), "One-Carbon Ring Expansion of Cycloalkanones to Conjugated Cycloalkenones: 2-Cyclohepten-1-one", Org. Synth., http://www.orgsyn.org/orgsyn/orgsyn/prepContent.asp?prep=cv6p0327 ; Coll. Vol. 6: 327
^ Nicholson Baker (2002). Double Fold: Libraries and the Assault on Paper. Vintage. ISBN 0375726217.
External links
Demonstration of the ignition of Diethylzinc in air Video - University of Nottingham
Diethylzinc, 15 wt.% solution in hexane MSDS commercial supplier
Diethylzinc purum MSDS commercial supplier
Diethylzinc MSDS commercial supplier
Diethylzinc US MSDS commercial supplier
Categories: Reagents for organic chemistry | Organozinc compounds | Highly Hazardous ChemicalsHidden categories: All articles with unsourced statements | Articles with unsourced statements from December 2007
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Recommend me korean ballads (not k-pop) please?
I really like korean indie, ballads and also jazz. Can you please recommend me some good songs? I'd prefer it if they were not k-pop, I like underground/independent bands and also solo singers, preferible male singers since I like ballads better when they're sung by men.
To mention some ones I like... Alex (알렉스) from Clazziquai has really grown on me recently. I really like My Vintage Romance and I've been loving Just Like Me too. Then, one of my all-time favorite k-songs is I'm Your Man by John Park (존박). I quite of like Brown Eyed Soul too but my fav is Jung Yup (정엽) as a solo singer.
About indie, I like 10cm (십센치) a lot, and also Autumn Vacation (가을 방학), Standing Egg (스탠딩에그) and Lala Sweet (랄라스윗). Two of my most played compilations rn are Life - Mint Paper Project vol.3 and Cracker: Compilation for a Bittersweet Love Story.
Can you please recommend me something? I'd really appreciate it! Thanks you!
Thanks for the singers you listed, with the exclusion of a few I haven't heard of most of them. I'll be sure to check them out. 
Here's my favorites, most are male singers, but I listed some female singers I really like:
Good Bye - KCM
You Make Me Smile - Na Yoon Kwon
Live Barely ft K.Will - The Name
Nothing Happened - Jung Yeop
Shoorooroop - Monday Kiz
Footprint - Monday Kiz
After This Night - Monday Kiz
Such a Man - Monday Kiz
Beautiful Woman - Lee Ki Chan
Same Pillow - Tei
This Is The Person - Kim Jong Kook
Don't Be Good to Me - Kim Jong Kook
Sunflower ft MJ - Gavy NJ
Address Unknown - Free Style
I'm Sorry - V.O.S.
I Was Full of Your Love (ft Gaeko) - Supreme Team
(Even though Supreme Team is hip-hop, this song is more like a ballad)
Love Meets at Cafe 'Galaxy' - 10cm
Last Love - Kim Bum Soo
Please - Kim Bum Soo
Heart, Please Stop - M.C. The Max
I Always Love You - DK (December)
Tears in Heaven - December
Love is So... - December
Can't You Come Back - December
Because Love is What I Learned - December
Like the First Time, Like Then ft Kang Min Kyung - Lee Seung Gi
Love Taught Me to Drink - Lee Seung Gi
The Classic - Magic Castle (Quite an old song, but very good)
Like a Child ft Alex - Kim Dong Ayul
Is Love So Easy ft Tae In - Namolla Family
Don't Leave Don't Leave - Brown Eyes
That Person - Lee Seung Chul
Memories Assemble Love - Park Hyo Shin
Always - Huh Gak
Don't Forget Me - Huh Gak
One While Living - 4MEN
I Think I Loved You - Jang Hye Jin
Confession - Hot Potato
A Single Word - Min Kyung Hoon
She - Min Kyung Hoon
It's Love Because It Hurts - Min Kyung Hoon
Suddenly - Kim Bo Young
Day After Day - Kim Bo Young
Men Are Also Helpless - Evan
There Was Only You - Kim Greem
You Are My Heaven - Kang Seung Yoon
With Tears - J.ae
Hello - Don Spike
Hurt - Yangpa
Diary - Navi
Turning Out For The Best - Navi
Also, I don't really know the name of this singer, but this very nice:
I don't know if you consider Seo In Young "kpop" but she's a very good ballad singer. Check out Lov-Elly. ZIA is also a very good singer.
Floyd Cramer Vintage Vol. 3